Experimental study on gas and particle emission characteristics of carbon black oxidation process in the presence of water and catalysts.

The study of oxidation characteristics of carbon black particle is the basis to investigate the regeneration process and characteristics of diesel particulate filter (DPF). Based on the fixed-bed test bench, the gas and particle emission characteristics of carbon black oxidation process in the presence of water are investigated under different temperatures, Printex-U (PU) masses, and catalysts. The experimental results show that the rise of temperature and PU mass increases the emissions of CO, CO2 and the total average particle number (PN). The oxidation efficiency (η) increases with temperature, but decreases with PU mass. The addition of catalysts promotes PU oxidation, and reduces CO emission. Due to the influence of particle diffusion, CeO2 has slightly lower efficiency than Pt/Al2O3 in the same ratio (1:1), but it is beneficial to significantly reduce particle emission, especially as the ratio increases (1:5). Water decreases CO and the η in PU oxidation, and the negative impact is gradually reduced after 3 % water concentration; However, the PN significantly increases, and expands the particle size range, particularly at high temperature and adding Pt/Al2O3 (from about 10 nm to 6- 30 nm, and a large number of particles with 30- 100 nm are produced). Additionally, the CO2/CO ratio of carbon black oxidation gradually increases with water concentration. Controlling DPF regeneration needs to strike a balance between the benefits on increasing oxidation efficiency and the potential negatives on particulate and harmful gas emission.

Combined feedforward and error-based active disturbance rejection control for diesel particulate filter thermal regeneration.

In this paper, a novel control solution, which combines a feedforward control law and an error-based version of the active disturbance rejection control (ADRC) scheme, is proposed for the exhaust gas temperature control during the thermal regeneration process of a diesel particulate filter in the exhaust line of a diesel engine. Attributed to the complexity of the controlled upstream diesel oxidation catalyst (DOC), its thermodynamics is firstly captured and characterized by a set of linear models through identification modeling. Then, a novel error-based ADRC controller, in which the separated components in conventional ADRC such as the extended state observer (ESO) and the feedback compensator are restructured into a single, modularized control function block, is designed by applying the identified nominal DOC model. In order to further unburden the error-based ESO for better achievements, a combined feedforward compensator is well designed on the basis of the principle of energy balance. Thus a hybrid, 2-degree-of-freedom (2-DOF) controller is developed for better dynamic performance of the controlled DOC system. Its stability performance is also analyzed in the work. The robustness and advantages of the presented hybrid control scheme are finally validated and compared with a well-tuned regular PID-based controller by means of extensive simulation and experimental tests. The results show that the proposed hybrid controller is capable of providing more accurate and faster temperature response and is less sensitive to the variation of system parameters and external disturbances. Moreover, as the error-based ADRC in the hybrid scheme takes the reference tracking error as its direct input and is compatible with the regular PID controller in terms of input and output interfaces, it herein provides an appealing control scheme for existing applications as a substitute for the conventional PID-based controllers to achieve improved performance.

Study on Emission Characteristics and Emission Reduction Effect for Construction Machinery under Actual Operating Conditions Using a Portable Emission Measurement System (Pems).

With the acceleration of urban construction, the pollutant emission of non-road mobile machinery such as construction machinery is becoming more and more prominent. In this paper, a portable emissions measurement system (PEMS) tested the emissions of eight different types of construction machinery under actual operating conditions and was used for idling, walking, and working under the different emission reduction techniques. The results showed that the pollutant emission of construction machinery is affected by the pollutant contribution of working conditions. According to different emission reduction techniques, the diesel oxidation catalyst (DOC) can reduce carbon monoxide (CO) by 41.6-94.8% and hydrocarbon (HC) by 92.7-95.1%, catalytic diesel particulate filter (CDPF) can reduce particulate matter (PM) by 87.1-99.5%, and selective catalytic reduction (SCR) using urea as a reducing agent can reduce nitrogen oxides (NOx) by 60.3% to 80.5%. Copper-based SCR is better than vanadium-based SCR in NOx reduction. In addition, the study found that when the enhanced 3DOC + CDPF emission reduction technique is used on forklifts, DOC has a "low-temperature saturation effect", which will reduce the emission reduction effect of CO and THC. The use of Burner + DOC + CDPF emission reduction techniques and fuel injection heating process will increase CO's emission factors by 3.2-3.5 and 4.4-6.7 times compared with the actual operating conditions.

Effect of Operating Parameters on Oxidation Characteristics of Soot under the Synergistic Action of Soluble Organic Fractions and Ash.

Diesel particulate filter is used to reduce particulate matter (PM) emission due to the stringent emission standards. The accumulated PM has been oxidized by the periodical regeneration method to avoid pressure buildup. The innovation of this study is to explore the oxidation performance of Printex-U (PU), which is mixed with ash and soluble organic fractions, under different operating conditions. Different aspects of operating parameters, such as the oxygen ratio in an O2/N2 atmosphere, total flow rate, initial PU mass, and heating rate, on PU oxidation properties have been critically discussed using a thermogravimetric analyzer. The oxygen ratio in the O2/N2 atmosphere is positively correlated with the oxidation characteristics of PU. The comprehensive oxidation index (S ) of PU under the 20% O2/80% N2 atmosphere increases by 184% compared with the 10% O2/90% N2 atmosphere. When the initial PU mass is 3 mg, the combustion stability coefficient (R w) and S reach the best values, which are 55.53 × 105 and 2.03 × 107 %2min-2 ° C-3, respectively. With the increase in the heating rate, the oxidation properties of PU become sensible and deflagration occurs easily, so that 10 °C/min heating rate is the best option. This study provides a theoretical basis for the optimization design of diesel particulates during the regeneration process.

Effect of Different Aging Conditions on the Soot Oxidation by Thermogravimetric Analysis.

Diesel particulate filter is an effective device to reduce diesel particulate emission. The particles in diesel particulate filter are usually affected by the aging of high-temperature exhaust gas before the regeneration process. In order to investigate the effect of aging conditions on the soot oxidation process, the effect of aging temperature and aging time on the oxidation process of carbon black (Printex-U, PU) and the PU/catalyst/ash mixture are studied by thermogravimetric analysis. The aging PU particles have lower starting temperature, peaking temperature, ending temperature, and activation energy. Compared with the particles without aging, the PU particles with a 400 °C aging temperature and 20 h aging time are able to reduce the activation energy from 191.2 to 158 kJ/mol. Low aging temperatures (200-300 °C) and the catalyst have a certain synergistic effect on the improvement of PU oxidation activity. The PU/CeO2 mixture with a 300 °C aging temperature and 20 h aging time decreases the activation energy from 178.4 to the lowest 113.6 kJ/mol. The addition of CaSO4 in PU particles cannot stop the improvement of its oxidation activity by aging, but it reduces the effect of aging. This work is helpful to reveal the mechanism of aging on PU and the PU/catalyst/ash mixture in air environment.

Thermogravimetric analysis of soot combustion in the presence of ash and soluble organic fraction.

Soot (Printex U, PU) combustion in the presence of ash and soluble organic fraction (SOF) was studied by thermogravimetric analysis (TGA). The comprehensive combustion index, combustion stability index and peak temperature were collected to evaluate the combustion performance of soot/ash/SOF mixtures. Compared with SiO2, Fe2O3 and CaSO4 nanoparticles, ZnO nanoparticles efficiently accelerate soot combustion with excellent oxygen carrying abilities. When the weight ratio of the PU/ZnO mixture is 1 : 1, this acceleration effect is maximized in the soot combustion process. The comprehensive combustion and combustion stability indices increase from 0.667 × 10-7%2 min-2 °C-3 and 23.53 × 105 to 1.296 × 10-7%2 min-2 °C-3 and 39.53 × 105, compared to pure PU, respectively. Compared with the PU/ZnO mixture, the soot combustion had inferior results after adding two oils as the simulative SOF. The 15W lubricant had the minimum negative impact compared to 0# diesel fuel. The comprehensive combustion and combustion stability indices reach the maximum values of 1.074 × 10-7%2 min-2 °C-3 and 33.29 × 105 at the 1 : 1 : 0.1 weight ratio of PU/ZnO/15W, which grew by 62% and 42% compared to pure PU, respectively. This work contributes to an understanding of the combined effect of ash and SOF on soot combustion.

Kinetic Study and Rate Coefficient Calculations of the Reaction of 1-Hydroxyethyl Radical with Nitric Oxide.

The kinetic study of the reaction of 1-hydroxyethyl radicals (CH3CHOH) with nitric oxide (NO) was performed over the temperature range of 200-1100 K and the pressure range of 1.0 × 10-5 to 10.0 bar. The geometries of all of the stationary points were optimized at the B3LYP/6-311++G(df,pd) level of theory, and the energetics were refined at the CCSD(T)/cc-pVTZ level of theory. Eight reaction pathways were explored, and they all consisted of a common first step involving the formation of a deep potential well. Three favorable pathways were confirmed, and they were the channels producing the adducts CH3CO(NHOH) and CH3NOHCHO and the products H2O and CH3CNO. The Rice-Ramsperger-Kassel -Marcus-canonical variational transition state theory method with Eckart tunneling correction was used to calculate the rate coefficients of the system. The predicted total rate coefficients agree well with the available literature data and show negative temperature dependence and positive pressure dependence. The reaction producing the adduct CH3CHOHNO in the entrance channel is dominant at 1.0 bar, and its branching ratio is almost 100% at a temperature less than 670 K. At 3.0 Torr, it is only dominant at a temperature less than 600 K.